You thus have seen that all the old “radiant matter” effects can be produced in tubes containing no metallic electrodes to volatilize. It may be suggested that the sides of the tube in contact with the outside poles become electrodes in this case, and that particles of the glass itself may be torn off and projected across, and so produce the effects. This is a strong argument, which fortunately can be tested by experiment. In the case of this tube (Fig. 23, P = 0.00068 millimeter, or 0.9 M), the bulb is made of lead glass phosphorescing blue under molecular bombardment. Inside the bulb, completely covering the part that would form the negative pole, A, I have placed a substantial coat of yttria, so as to interpose a layer of this earth between the glass and the inside of the tube. The negative and positive poles are silver disks on the outside of the bulb, A being the negative and B the positive poles. If, therefore, particles are torn off and projected across the tube to cause phosphorescence, these particles will not be particles of glass, but of yttria; and the spot of phosphorescent light, C, on the opposite side of the bulb will not be the dull blue of lead glass, but the golden yellow of yttria. You see there is no such indication; the glass phosphoresces with its usual blue glow, and there is no evidence that a single particle of yttria is striking it.
[Illustration: Fig. 22.—Pressure = 0.000076 MM. = 0.1 M.]
[Illustration: Fig. 23.—Pressure = 0.00068 MM. = 0.9 M.]
Witnessing these effects I think you will agree I am justified in adhering to my original theory, that the phenomena are caused by the radiant matter of the residual gaseous molecules, and certainly not by the torn-off particles of the negative electrode.
PHOSPHORESCENCE IN HIGH VACUA.
I have already pointed out that the molecular motions rendered visible in a vacuum tube are not the motions of molecules under ordinary conditions, but are compounded of these ordinary or kinetic motions and the extra motion due to the electrical impetus.
Experiments show that in such tubes a few molecules may traverse more than a hundred times the mean free path, with a correspondingly increased velocity, until they are arrested by collisions. Indeed, the molecular free path may vary in one and the same tube, and at one and the same degree of exhaustion.
Very many bodies, such as ruby, diamond, emerald, alumina, yttria, samaria, and a large class of earthy oxides and sulphides, phosphoresce in vacuum tubes when placed in the path of the stream of electrified molecules proceeding from the negative pole. The composition of the gaseous residue present does not affect phosphorescence; thus, the earth yttria phosphoresces well in the residual vacua of atmospherical air, of oxygen, nitrogen, carbonic anhydride, hydrogen, iodine, sulphur and mercury.