it, in fully one-half, might I not say nine-tenths,
of existing furnaces and close stoves. But in
an ordinary gas retort the heat required to distill
the gas is furnished by an outside fire; this is only
necessary when you require lighting gas, with no admixture
of carbonic acid and as little carbonic oxide as possible.
If you wish for heating gas, you need no outside fire;
a small fire at the bottom of a mass of coal will
serve to distill it, and you will have most of the
carbon also converted into gas. Here, for instance,
is Siemens’ gas producer. The mass of coal
is burning at the bottom, with a very limited supply
of air. The carbonic acid formed rises over the
glowing coke, and takes up another atom of carbon to
form the combustible gas carbonic oxide. This
and the hot nitrogen passing over and through the
coal above distill away its volatile constituents,
and the whole mass of gas leaves by the exit pipe.
Some art is needed in adjusting the path of the gases
distilled from the fresh coal with reference to the
hot mass below. If they pass too readily, and
at too low a temperature, to the exit pipe, this is
apt to get choked with tar and dense hydrocarbons.
If it is carried down near or through the hot fuel
below, the hydrocarbons are decomposed over much,
and the quality of the gas becomes poor. Moreover,
it is not possible to make the gases pass freely through
a mass of hot coke; it is apt to get clogged.
The best plan is to make the hydrocarbon gas pass
over and near a red-hot surface, so as to have its
heaviest hydrocarbons decomposed, but so as to leave
all those which are able to pass away as gas uninjured,
for it is to the presence of these that the gas will
owe its richness as a combustible material, especially
when radiant heat is made use of.
The only inert and useless gas in an arrangement like
this is the nitrogen of the air, which being in large
quantities does act as a serious diluent. To
diminish the proportion of nitrogen, steam is often
injected as well as air. The glowing coke can
decompose the steam, forming carbonic oxide and hydrogen,
both combustible. But of course no extra energy
can be gained by the use of steam in this way; all
the energy must come from the coke, the steam being
already a perfectly burned product; the use of steam
is merely to serve as a vehicle for converting the
carbon into a convenient gaseous equivalent.
Moreover, steam injected into coke cannot keep up the
combustion; it would soon put the fire out unless air
is introduced too. Some air is necessary to keep
up the combustion, and therefore some nitrogen is
unavoidable. But some steam is advisable in every
gas producer, unless pure oxygen could be used instead
of air; or unless some substance like quicklime, which
holds its oxygen with less vigor than carbon does,
were mixed with the coke and used to maintain the heat
necessary for distillation. A well known gas
producer for small scale use is Dowson’s.
Steam is superheated in a coil of pipe, and blown through
glowing anthracite along with air. The gas which
comes off consists of 20 per cent. hydrogen, 30 per
cent. carbonic oxide, 3 per cent. carbonic acid, and
47 per cent. nitrogen. It is a weak gas, but
it serves for gas engines, and is used, I believe,
by Thompson, of Leeds, for firing glass and pottery
in a gas kiln. It is said to cost 4d. per 1,000
ft., and to be half as good as coal gas.