so small that they hardly ever meet—they
would have to be infinitely small to
never meet—that,
in fact, they meet so seldom, in comparison with the
number of times their courses—are turned
through large angles by attraction, that the influence
of these surely attractive collisions is preponderant
over that of the comparatively very rare impacts from
actual contact. Thus, after all, the train of
speculation suggested by Davy’s “Repulsive
Motion” does not allow us to escape from the
idea of true repulsion, does not do more than let us
say it is of no consequence, nor even say this with
truth, because, if there are impacts at all, the nature
of the force during the impact and the effects of
the mutual impacts, however rare, cannot be evaded
in any attempt to realize a conception of the kinetic
theory of gases. And in fact, unless we are satisfied
to imagine the atoms of a gas as mathematical points
endowed with inertia, and as, according to Boscovich,
endowed with forces of mutual, positive, and negative
attraction, varying according to some definite function
of the distance, we cannot avoid the question of impacts,
and of vibrations and rotations of the molecules resulting
from impacts, and we must look distinctly on each
molecule as being either a little elastic solid or
a configuration of motion in a continuous all-pervading
liquid. I do not myself see how we can ever permanently
rest anywhere short of this last view; but it would
be a very pleasant temporary resting-place on the
way to it if we could, as it were, make a mechanical
model of a gas out of little pieces of round, perfectly
elastic solid matter, flying about through the space
occupied by the gas, and colliding with one another
and against the sides of the containing vessel.
This is, in fact, all we have of the kinetic theory
of gases up to the present time, and this has done
for us, in the hands of Clausius and Maxwell, the
great things which constitute our first step toward
a molecular theory of matter. Of course from
it we should have to go on to find an explanation
of the elasticity and all the other properties of the
molecules themselves, a subject vastly more complex
and difficult than the gaseous properties, for the
explanation of which we assume the elastic molecule;
but without any explanation of the properties of the
molecule itself, with merely the assumption that the
molecule has the requisite properties, we might rest
happy for a while in the contemplation of the kinetic
theory of gases, and its explanation of the gaseous
properties, which is not only stupendously important
as a step toward a more thoroughgoing theory of matter,
but is undoubtedly the expression of a perfectly intelligible
and definite set of facts in Nature.