It was in the year 1819 that Sir David Brewster published the first account of his long and important series of observations upon the physical peculiarities of tabasheer (Phil. Trans., vol. cix., 1819, p. 283). The specimens which he first examined were obtained from India by Dr. Kennedy, by whom they were given to Brewster.
Brewster found the specimens which he examined to be perfectly isotropic, exercising no influence in depolarizing light. When heated, however, it proved to be remarkably phosphorescent. The translucent varieties were found to transmit a yellowish and to reflect a bluish white light—or, in other words, to exhibit the phenomenon of opalescence. When tabasheer is slightly wetted, it becomes white and opaque; but when thoroughly saturated with water, perfectly transparent.
By preparing prisms of different varieties of tabasheer, Brewster proceeded to determine its refractive index, arriving at the remarkable result that tabasheer “has a lower index of refraction than any other known solid or liquid, and that it actually holds an intermediate place between water and gaseous bodies!” This excessively low refractive power Brewster believes to afford a complete explanation of the extraordinary behavior exhibited by tabasheer when wholly or partially saturated with fluids. A number of interesting experiments were performed by saturating the tabasheer with oils of different refractive powers, and by heating it in various ways and under different conditions, and also by introducing carbonaceous matter into the minute pores of the substance by setting fire to paper in which fragments were wrapped.
The mean of experiments undertaken by Mr. James Jardine, on behalf of Brewster, for determining the specific gravity of tabasheer, gave as a result 2.235. From these experiments Brewster concluded that the space occupied by the pores of the tabasheer is about two and a half times as great as that of the colloid silica itself!
From this time forward Brewster seems to have manifested the keenest interest in all questions connected with the origin and history of a substance possessing such singular physical properties. By the aid of Mr. Swinton, secretary to the government at Calcutta, he formed a large and interesting collection of all the different varieties of tabasheer from various parts of India. He also obtained specimens of the bamboo with the tabasheer in situ. In 1828 he published an interesting paper on “The Natural History and Properties of Tabasheer” (Edinburgh Journal of Science, vol. viii., 1828, p. 288), in which he discussed many of the important problems connected with the origin of the substance. From his inquiries and observations, Brewster was led to conclude that tabasheer was only produced in those joints of bamboos which are in an injured, unhealthy, or malformed condition, and that the siliceous fluid only finds its way into the hollow spaces between the joints of the stem when the membrane lining the cavities is destroyed or rent by disease.